受限透视角度下超声波CT温度场诊断技术

超声波CT一种热测量方法,具有不接触、对温度场不干扰的优点。本文发展一种新的超声波CT再现方法,用于解决受限透视角度所产生的信息量不足的问题。新的超声波CT再现算法建立在逆矩阵变换的基础上,它不同于通常的采用SL过滤器的所谓FBPCT再现方式。论文中描述了三种CT迭代再现算法,用计算机模拟结果和三维温度场测量实验数据验证了再现算法的可靠性。同时根据计算和实验结果,建议在受限的透视角度情况下,迭代方法采用修正的正则最小二乘法CGM是合适的。     

Invasion of Gleditsia triacanthos in Lithraea ternifolia Montane Forests of Central Argentina

Gleditsia triacanthos and the native dominant Lithraea ternifolia in montane forests of central Argentina, considering life history and demographic traits of both the alien and the native species and different site conditions for population growth (good and bad sites). Matrix models are applied to project the consequences of differences in vital rates for population growth. Analyzing these models helps identify which life cycle transitions contributed most to population growth. Obtained population growth rates are considered to assess predicted rates of spread using the reaction-diffusion (R-D) model. G. triacanthos presents many of the life history traits that confer plants high potential for invasiveness: fast growth, clonal and sexual reproduction, short juvenile period, high seed production, and high seed germinability. These traits would ensure G. triacanthos invasive success and the displacement of the slow-growing, relatively less fecund native L. ternifolia. However, since disturbance and environmental heterogeneity complicate the invasibility pattern of G. triacanthos in these montane forests, the outcome of the invasion process is not straightforward as could be if only life history traits were considered. Great variation in demographic parameters was observed between populations of each species at good and bad sites. Though both good and bad sites signified increasing or at least stable populations for G. triacanthos, for L. ternifolia bad sites represented local extinction. Analyzing the results of matrices models helps design the optimal management for the conservation of L. ternifolia populations while preventing the invasion by G. triacanthos. The predicted asymptotic rate of spread for G. triacanthos at the good site was fourfold greater than the predicted one for L. ternifolia, although the difference was much smaller considering the bad site. The usefulness of the R-D model to study this invasion system is discussed.     

岩矿样品X射线荧光分析中多元素体系理论α系数的计算和应用

本文提出了岩矿样品X射线荧光分析中多元素体系的理论α系数的一种计算方法。假设试样由n个组分组成,其各组分平均含量为Cl(Cl=1,2,3,…k,……n),然后,假设某一组分的含量Cl相对于平均含量Cl有一微小变化量ΔC,并使每个组分相应变化一次,用基本参数法方程计算理论X射线相对强度;再按一定的数学模式计算相应的基本α系数,混合α系数和修正α系数。以实例计算了用于地质样品分析的各种理论α系数,应用于实际分析中结果令人满意。     

Field-scale effective matrix diffusion coefficient for fractured rock: results from literature survey

Matrix diffusion is an important mechanism for solute transport in fractured rock. We recently conducted a literature survey on the effective matrix diffusion coefficient, D_m^e, a key parameter for describing matrix diffusion processes at the field scale. Forty field tracer tests at 15 fractured geologic sites were surveyed and selected for the study, based on data availability and quality. Field-scale D_m^e values were calculated, either directly using data reported in the literature, or by reanalyzing the corresponding field tracer tests. The reanalysis was conducted for the selected tracer tests using analytic or semi-analytic solutions for tracer transport in linear, radial, or interwell flow fields. Surveyed data show that the scale factor of the effective matrix diffusion coefficient (defined as the ratio of D_m^e to the lab-scale matrix diffusion coefficient, D_m, of the same tracer) is generally larger than one, indicating that the effective matrix diffusion coefficient in the field is comparatively larger than the matrix diffusion coefficient at the rock-core scale. This larger value can be attributed to the many mass-transfer processes at different scales in naturally heterogeneous, fractured rock systems.Furthermore, we observed a moderate, on average trend toward systematic increase in the scale factor with observation scale. This trend suggests that the effective matrix diffusion coefficient is likely to be statistically scale-dependent. The scale-factor value ranges from 0.5 to 884 for observation scales from 5 to 2000 m. At a given scale, the scale factor varies by two orders of magnitude, reflecting the influence of differing degrees of fractured rock heterogeneity at different geologic sites. In addition, the surveyed data indicate that field-scale longitudinal dispersivity generally increases with observation scale, which is consistent with previous studies. The scale-dependent field-scale matrix diffusion coefficient (and dispersivity) may have significant implications for assessing long-term, large-scale radionuclide and contaminant transport events in fractured rock, both for nuclear waste disposal and contaminant remediation.     

Application of an ELISA to the quantification of carbamazepine in ground, surface and wastewaters and validation with LC-MS/MS

Carbamazepine is a psychiatric pharmaceutical widely detected in aquatic environments. Due to its generalized occurrence and environmental persistence it might be considered as an anthropogenic pollution indicator. In this research, a previously developed enzyme-linked immunosorbent assay (ELISA), based on a commercial monoclonal antibody, was applied to the quantification of carbamazepine in ground, surface and wastewaters and results were validated by liquid chromatography-tandem mass spectrometry (LC-MS/MS).The performance of the applied ELISA methodology was tested in the presence of high concentrations of sodium chloride and dissolved organic matter. The method was not significantly affected by matrix effects, being adequate for the quantification of carbamazepine in environmental samples, even without sample pre-treatment. This method allows the quantification of carbamazepine in the range of 0.03-10 μg L⁻¹, with a relative error lower than 30%. Due to a pH dependent cross-reactivity with cetirizine, an antihistaminic drug, the assay also enabled the quantification of cetirizine in the samples.The application of the developed method to the quantification of carbamazepine was performed by using environmental samples with very different matrices, collected in the geographical area of Ria de Aveiro, an estuarine system located in the North of Portugal. Carbamazepine was detected in all analyzed wastewater samples and in one surface water with concentrations between 0.1 and 0.7 μg L⁻¹. Validation with LC-MS/MS revealed that results obtained by ELISA are 2-28% overestimated, which was considered highly satisfactory due to the absence of sample pre-treatments.     

模糊矩阵法在校园声环境质量评价中的应用

由于噪声及其感受主体均具有不确定性的特点,拟采用模糊综合评价方法对声环境质量进行评价,从而使评价结果更具客观性和合理性。本文通过对S大学声环境质量的现状监测并结合在校师生主观感受调查结果,运用模糊矩阵法对校园声环境质量进行综合评价,并对校园声环境质量与教学生活的适宜度进行了分析论证。     

地面封闭对域市水环境的危害

针对全球出现的城市水环境问题,本文提出了地面封闭的概念,阐述了地面封闭的危害,认为地面封闭减少和阻止了大气降水对地表水和地下水的补给,破坏了区域性的水循环,是形成一些城市水环境问题的重要原因之一。认识地面封闭的危害,对解决这些城市水环境问题将具有巨大的社会经济和生态意义。     

Rock matrix diffusivity determinations by in-situ electrical conductivity measurements

A fast method to determine rock matrix diffusion properties directly in the bedrock would be valuable in the investigation of a possible site for disposal of nuclear waste. An "effective diffusivity borehole log" would provide important information on the variability of this entity over the area studied. As opposed to traditional matrix diffusion laboratory experiments, electrical conductivity measurements are fast, inexpensive and also easy to carry out in-situ. In this study, electrical resistivity data from borehole logging, as well as from measurements on the actual core, is evaluated with the purpose of extracting matrix diffusivity data. The influence of migration of ions in the electrical double layer, which can be of great importance in low ionic strength pore water, is also considered in evaluating the in-situ data to accurately determine the effective pore diffusivity. The in-situ data compare fairly well to those measured in the rock core.     

UPLC-MS/MS法分析土壤中氨基甲酸酯类农药残留的基质效应研究

采用加速溶剂萃取处理土壤样品,用超高效液相色谱串联质谱法测定样品中15种氨基甲酸酯类农药残留,方法在5.00μg/L～200μg/L范围内线性良好,检出限为0.3μg/kg～0.5μg/kg,加标回收率为78.9％ ～116％,6次测定结果的RSD为0.7％ ～15.7％.试验表明:不同地域的6种标准土壤对15种目标物...     

基于STAMP模型的建筑事故致因因素定量分析方法研究

为揭示建筑安全事故致因因素间的相互关系从而对其进行有效预防和控制，探讨1种STAMP模型的定量分析方法，用于深入剖析事故致因因素间的逻辑关系和属性特征。基于STAMP系统事故理论模型，从建筑工程安全控制结构入手逐层定性分析事故的致因因素；引入灰色DEMATEL与ISM相结合的方法对系统事故间的复杂逻辑关系进行层级划分；运用MICMAC分析计算各致因因素的驱动力和依赖度数值并判断其属性类别。结果表明:提出的定量分析方法运用到江西丰城冷却塔坍塌事故中的分析结果与事故调查报告相契合，能较全面地说明各层次结构间的相互作用。